Elahera chrysoberyl alexandrite: chromium-iron absorption lines and daylight color shift?
What specific spectroscopic transmission windows produce the dramatic green-to-red color change in natural Ceylon alexandrite under incandescent tungsten illumination?
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5 Answers from travellers
The optical color-change phenomenon in Ceylon alexandrite (chrysoberyl / BeAl2O4:Cr3+) is governed by trace chromium substitution within the aluminum octahedral crystal sites. Chromium creates a broad, intense absorption band centered in the yellow-orange spectrum (around 580nm), while leaving two distinct transmission windows open: one in the blue-green region (around 490nm) and one in the deep red region (above 650nm). When illuminated by balanced daylight (rich in blue-green wavelengths), the stone transmits green; under warm incandescent or candle light (rich in red wavelengths), the red transmission window dominates, shifting body color to purplish-red.
Sri Lankan alexandrites frequently display a lighter, yellowish-green daylight color that shifts to a brownish-red under tungsten lamps, distinct from Ural stones.
Look for strong trichroism under a calcite dichroscope: showing green, orange-yellow, and purple-red when rotated along three principal optical axes.
Synthetic flux-grown and Czochralski-pulled alexandrites flood the market; natural stones are identified by two-phase inclusions and stepping twin lines.
High-clarity unheated Ceylon alexandrites exceeding 2 carats with an 80%+ color change command premium pricing at international gemstone auctions.
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