Geuda sapphire charcoal furnace reduction: sealing crucible lids with refractory clay mud?
5 Answers from travellers
Thermal alteration of milky Geuda corundum in Ratnapura requires maintaining strict reducing conditions at temperatures between 1600°C and 1750°C. Rough stones are packed into high-purity graphite or sillimanite crucibles filled with carbonaceous charcoal powder. The crucible lid is sealed with a thick collar of refractory fireclay mixed with zircon sand and sodium silicate. When fired inside oil-and-air blown Lakka furnaces, the charcoal consumes internal oxygen (forming carbon monoxide CO gas). This reducing atmosphere forces iron ions from Fe3+ into Fe2+, which bonds with Ti4+ to trigger intense blue charge-transfer coloration.
If the refractory clay lid cracks during firing, outside air enters, oxidizing the charge and producing unwanted yellow-green overtones across sapphire parcels.
Firing runs last 6 to 12 hours, followed by a controlled 24-hour cooling ramp down to prevent thermal shock fractures around internal mineral crystals.
NGJA testing protocols mandate testing treated parcels with FTIR spectroscopy; heated stones display distinctive 3309 cm-1 absorption series.
Traditional Lakka blowers utilize recycled automotive diesel injectors powered by electric air blowers to reach high melting temperatures.
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